I-Catalyst
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I-catalyst yokutshintsha ubushushu obuphantsi
Isixhobo sokutshintsha ubushushu obuphantsi:
Isicelo
I-CB-5 kunye ne-CB-10 isetyenziselwa uGuquko kwi-synthesis kunye neenkqubo zokuvelisa i-hydrogen
Ukusebenzisa amalahle, i-naphtha, irhasi yendalo kunye nerhasi ye-oyile yentsimi njengezokutya, ngakumbi iziguquli zokutshintsha ubushushu be-axial-radial..
Iimpawu
I-catalyst ineenzuzo zomsebenzi kwiqondo lokushisa eliphantsi.
Ubuninzi bobuninzi obusezantsi, iCopper ephezulu kunye nomphezulu weZinc kunye namandla angcono omatshini.
Iimpawu zomzimba kunye neekhemikhali
Uhlobo
CB-5
CB-5
CB-10
Imbonakalo
Iipilisi ezimnyama ze-cylindrical
Ububanzi
5mm
5mm
5mm
Ubude
5mm
2.5mm
5mm
Unizi lolwapho kuyiwa khona
1.2-1.4kg / l
Amandla eRadialcrushing
≥160N/cm
≥130 N/cm
≥160N/cm
CuO
40±2%
ZnO
43±2%
Iimeko zokusebenza
Ubushushu
180-260°C
Uxinzelelo
≤5.0MPa
Isantya sesithuba
≤3000h-1
Umlinganiselo wegesi yomphunga
≥0.35
Faka i-H2Scontent
≤0.5ppmv
Ingenisa uCl-1umxholo
≤0.1ppmv
I-ZnO desulfurization Catalyst enomgangatho ophezulu kunye nexabiso elikhuphisanayo
I-HL-306 iyasebenza kwi-desulfurization yentsalela yeegesi eziqhekekayo okanye i-syngas kunye nokucocwa kweegesi zesondlo
iinkqubo ze-organic synthesis. Ilungele ukusetyenziswa kobushushu obuphezulu (350–408°C) nangaphantsi (150–210°c).
Iyakwazi ukuguqula isulfure ephilayo elula ngelixa ifunxa isulfure ye-inorganic kumsinga werhasi. Impendulo engundoqo ye
inkqubo desulfurization imi ngolu hlobo lulandelayo:
(1) Ukusabela kwe-zinc oxide kunye ne-hydrogen sulfide H2S+ZnO=ZnS+H2O
(2) Ukusabela kwe-zinc oxide kunye nezinye iikhompawundi zesulfure ezilula ngeendlela ezimbini ezinokwenzeka.
2.iiPropati zoMzimba
Imbonakalo ezimhlophe okanye ukukhanya-tyheli extrudates Ubungakanani besuntswana, mm Φ4×4–15 Ukuxinana ngobuninzi, kg/L 1.0-1.3 3.Umgangatho woMgangatho
amandla okutyumza, N/cm ≥50 ilahleko ekuphelelweni, % ≤6 Ukutyhoboza umthamo wesulfure, wt% ≥28(350°C)≥15(220°C)≥10(200°C) 4. IMeko yokuSebenza eqhelekileyo
I-Feedstock: irhasi ye-synthesis, irhasi yentsimi yeoli, igesi yendalo, irhasi yamalahle. Inokuphatha umjelo werhasi ngesulfure engaphiliyo iphezulu
njengoko 23g/m3 kunye isidanga esanelisayo zokucoca. Iyakwazi nokuhlambulula umjelo werhasi ukuya kuthi ga kwi-20mg/m3 yelula ngolo hlobo
sulphur ephilayo njenge-COS ukuya ngaphantsi kwe-0.1ppm.
5.Ilayisha
Ukulayisha ubunzulu: I-L/D ephezulu (min3) iyacetyiswa. Ulungelelwaniso lweereactor ezimbini kuthotho kunokuphucula ukusetyenziswa
ukusebenza kakuhle kwe-adsorbent.
Ilayisha inkqubo:
(1)Coca i-reactor phambi kokulayisha;
(2)Beka iigridi ezimbini ezingenakutyiwa ezinobukhulu obuncinci bemesh kune-adsorbent;
(3)Layisha umaleko oyi-100mm we-Φ10—20mm iisphere ezizii-refractory kwiigridi ezingenasici;
(4)Jonga i-adsorbent ukususa uthuli;
(5)Sebenzisa isixhobo esikhethekileyo ukuqinisekisa ukuhanjiswa ngokulinganayo kwe-adsorbent ebhedini;
(6)Hlola ukufana kwebhedi ngexesha lokulayisha. Xa kufuneka umsebenzi wangaphakathi wereactor, ipleyiti yomthi kufuneka ibekwe kwi-adsorbent ukuze umqhubi ame phezu kwayo.
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nokusasazwa komsinga werhasi.
6.Ukuqalisa
(1)Tshintsha inkqubo nge-nitrogen okanye ezinye iigesi ezingasebenziyo de i-oxygen concentration kwigesi ibe ngaphantsi kwe-0.5%;
(2)Tshisa umjelo wesondlo ngenitrogen okanye igesi yefidi phantsi koxinzelelo olungqongileyo okanye oluphakamileyo;
(3)Isantya sokufudumeza: 50°C/h ukusuka kubushushu begumbi ukuya kwi-150°C (ngenitrogen); I-150 ° C ye-2 h (xa i-idium medium ishushu
itshintshelwe kwigesi yokutya), 30°C/h ngaphezulu kwe-150°C de ubushushu obufunekayo bufunyenwe.
(4) Lungisa uxinzelelo ngokuthe chu de uxinzelelo lomsebenzi lufunyenwe.
(5)Emva kokufudumeza kwangaphambili kunye nokuphakama koxinzelelo, inkqubo kufuneka iqale iqhutywe kwisiqingatha somthwalo we-8h. Emva koko phakamisa i
layisha ngokuthe chu xa umsebenzi uzinza de usebenze ngokupheleleyo.
7.Cima
(1)Ubonelelo olungxamisekileyo lokuvala irhasi (i-oyile).
Vala iivalvu zokungena neziphumayo. Gcina ubushushu kunye noxinzelelo. Ukuba kuyimfuneko, sebenzisa initrogen okanye ihydrogen-nitrogen
igesi ukugcina uxinzelelo lokuthintela uxinzelelo olubi.
(2) Ukutshintsha kwe-adsorbent ye-desulfurization
Vala iivalvu zokungena neziphumayo. Yehlisa ngokuthe ngcembe iqondo lobushushu kunye noxinzelelo kwimeko ye-ambient. Emva koko wahlule i
i-reactor desulfurization ukusuka kwinkqubo yemveliso. Buyisela ireactor ngomoya de uxinzeleko lweoksijini engaphezulu kwama-20% lufunyenwe. Vula i-reactor kwaye ukhuphe i-adsorbent.
(3) Ukugcinwa kwezixhobo (ulungiso)
Qwalasela inkqubo efanayo njengoko kubonisiwe ngasentla ngaphandle kokuba uxinzelelo kufuneka luthotywe nge-0.5MPa/10min kunye ne-temp.
ithotywe ngokwemvelo.
I-adsorbent engalayishwanga iya kugcinwa kwimigangatho eyahlukeneyo. Hlalutya iisampulu ezithathwe kumaleko ngamnye ukumisela
ubume kunye nobomi benkonzo ye-adsorbent.
8.Ukuthutha kunye nokugcinwa
1
ungcoliso.
(2) Ukugingqika, ukungqubana kunye nokungcangcazela okunobundlobongela kufuneka kuphetshwe ngexesha lothutho ukunqanda ukugutyungelwa
i-adsorbent.
(3)Imveliso ye-adsorbent kufuneka ithintelwe ekudibaneni neekhemikhali ngexesha lokuthutha kunye nokugcinwa.
(4) Imveliso ingagcinwa iminyaka emi-3-5 ngaphandle kokuwohloka kweempawu zayo ukuba itywinwe ngokufanelekileyo.
Ukufumana iinkcukacha ezithe vetshe malunga neemveliso zethu, nceda ungalibazisi ukuqhagamshelana nam.
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I-Nickel Catalyst Njenge-Amoniya yokuBola kweCatalyst
I-Nickel Catalyst Njenge-Amoniya yokuBola kweCatalyst
I-ammonia yokubola i-catalyst luhlobo lwe-sec. i-reaction catalyst, esekelwe kwi-nickel njengenxalenye esebenzayo kunye ne-alumina njengomphathi oyintloko. Isetyenziswa ikakhulu kwisityalo se-ammonia sohlaziyo lwesibini lwe-hydrocarbon kunye nokubola kwe-ammonia
isixhobo, sisebenzisa i-hydrocarbon enegesi njengento ekrwada. Inozinzo oluhle, umsebenzi omhle, kunye namandla aphezulu.
Isicelo:
Isetyenziswa kakhulu kwisityalo se-ammonia sohlaziyo lwesibini lwe-hydrocarbon kunye nesixhobo sokubola kwe-ammonia,
usebenzisa i-hydrocarbon enegesi njengemathiriyeli ekrwada.
1. IiPropati zoMzimba
Imbonakalo Isileyiti esingwevu raschig iringi Ubungakanani besuntswana, mmDiameter x Ubude x Ukutyeba 19x19x10 Amandla okutyumza,N/isuntswana Min.400 Ukuxinana ngobuninzi, kg/L 1.10 - 1.20 Ilahleko ekuphelelweni, wt% Ubuninzi.20 Umsebenzi weCatalytic 0.05NL CH4/h/g I-Catalyst 2. Ukuqulunqwa kwemichiza:
Umxholo weNickel (Ni), % Umz.14.0 SiO2, % Ubuninzi.0.20 Al2O3, % 55 CaO, % 10 Fe2O3, % Ubuninzi.0.35 K2O+Na2O, % Ubuninzi.0.30 Ukumelana nobushushu:ukusebenza kwexesha elide phantsi kwe-1200 ° C, ukunganyibiliki, ukungafihli, ukungahambi kakuhle, ukuzinza okuhle kunye namandla aphezulu.
Ipesenti yezinto ezincinci ezisezantsi (ipesenti engaphantsi kwe-180N / i-particle): max.5.0%
Isalathisi sokumelana nobushushu: ukungabambeleli kunye nokwaphuka kwiiyure ezimbini kwi-1300 ° C.
3. Umqathango wokuSebenza
Iimeko zenkqubo Uxinzelelo, MPa Iqondo lobushushu, °C Isantya sendawo yeammonia, hr-1 0.01 -0.10 750-850 350-500 Izinga lokubola kwe-ammonia 99.99% (min) 4. Ubomi benkonzo: iminyaka emi-2
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Umgangatho ophezulu we-wholesale catalyst yoshishino lwe-hydrogenation
I-Hydrogenation industry catalyst
Nge-alumina njengomthwali, i-nickel njengeyona nto isebenzayo, i-catalyst isetyenziswa ngokubanzi kwi-aviation parafiation ukuya kwi-hydrogenation dearomatization, benzene hydrogenation ukuya kwi-cyclohexane, phenol hydrogenation ukuya kwi-cyclohexanol hydrotreating, i-hydrofining ye-industrial crude hexane, kunye ne-organic rated hydrogensphant hydrogensation ye-unsa. iihydrocarbons ezinevumba elimnandi, njengeoyile emhlophe, i-oyile ye-oyile ye-hydrogenation. Ingasetyenziselwa i-desulfurization yesigaba solwelo, kunye ne-agent ekhuselayo yesulfure kwinkqubo yokuguqulwa kwe-catalytic. I-catalyst inamandla aphezulu, umsebenzi ogqwesileyo, kwinkqubo yokusulungekisa i-hydrogenation, enokwenza i-hydrocarbon enevumba elimnandi okanye engaxutywanga phantsi ukuya kwinqanaba le-ppm. I-catalyst iyancipha urhulumente ozinzisayo unyango.
Ngokuthelekisa, i-catalyst esetyenziswe ngempumelelo kwizityalo ezininzi kwihlabathi, ingcono kuneemveliso zasekhaya ezifanayo.
Iimpawu zomzimba kunye neekhemikhali:Into Isalathiso Into Isalathiso Imbonakalo cylinder emnyama Ukuxinana ngobuninzi ,kg/L 0.80-0.90 Ubungakanani besuntswana, mm Φ1.8×-3-15 Indawo engaphezulu,m2/g 80-180 Amacandelo amachiza NiO-Al2O3 Amandla okutyumza ,N/cm ≥ 50 Iimeko zovavanyo lomsebenzi:
Iimeko zeNkqubo Uxinzelelo lwenkqubo
MpaI-Hydrogen ye-Nitrogen yesantya sesithuba hr-1 Ubushushu
°CIsantya sendawo yePhenol
hr-1Hydrogen phenol ratio
mol/molUxinzelelo oluqhelekileyo 1500 140 0.2 20 Inqanaba lomsebenzi I-Feedstock: i-phenol, ukuguqulwa kwe-phenol min 96% Ukufumana iinkcukacha ezithe vetshe malunga neemveliso zethu, nceda uzive ukhululekile ukuqhagamshelana nam.