IZIQULATHO
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I-AGO-0X5L Catalyst ye-PA Production evela kwi-0-xylene
Ukuma kweMichiza
I-V-Tl i-oxide yentsimbi egqunywe kwi-inert carrier
Iipropati Zomzimba
Ubume beCatalyst
Umsesane ongenanto rhoqo
Ubungakanani beCatalyst
7.0*7.0*3.7±0.1mm
Unizi lolwapho kuyiwa khona
1.07±0.5kg/L
Inani leLeya
5
Iiparamitha zokuSebenza
Imveliso ye-Oxidation
113-115wt% emva konyaka wokuqala
112-114wt% emva konyaka wesibini
110-112wt% emva konyaka wesithathu
Ubushushu bendawo eshushu
400-440℃(Eqhelekileyo)
Ukwehla koxinzelelo lwe-Catalyst
0.20-0.25 IBar(G)
Ubomi beCatalyst
> iminyaka emi-3
Imeko yokusetyenziswa kweZityalo zoRhwebo
Ukuhamba komoya
4. 0NCM/ityhubhu/h
Umthwalo we-O-xylene
320g/ityhubhu/h (Eqhelekileyo)
400g/ityhubhu/h(Ubukhulu)
I-0-xylene yoxinaniso
80g/NCM (Eqhelekileyo)
100g/NCM (Ubukhulu)
Ubushushu beTyuwa
350-375℃
(Ngokwemeko yesityalo somthengi)
Iimpawu zeMveliso kunye neeNkonzo I-AGO-0X5L, inani le-catalyst layers yi-5 layers, ephuhliswayo kwaye iphuculwe ngokusekelwe kwi-phthalic ephuculweyo yeteknoloji ye-hydride catalyst eYurophu. Olu hlobo lwe-catalyst luneempawu zomsebenzi ophezulu kunye nesivuno esiphezulu, kwaye umgangatho wemveliso uzinzile kwaye unokwethenjelwa. Okwangoku, uphando lwe-catalyst kunye nophuhliso kunye nokuveliswa kovavanyo luye lwagqitywa, kwaye imveliso ye-industria iya kwenziwa kungekudala.
Ukubonelela ngokulayishwa kwe-catalyst kunye nokuqaliswa kweenkonzo zobugcisa.
Imbali yeMveliso 2013—————————————–R&D iqalile kwaye iyaphumelela
Ekuqaleni kuka-2023—————-R&D iphinde yaqalwa, uqinisekiso lugqityiwe
Phakathi 2023———————–Industrial trial production
Ekupheleni kuka-2023——————————Silungele ukuziswa
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I-AOG-MAC01 ibhedi esisigxina yebenzene Oxidation ukuya kwi-Maleic Anhydride catalyst
I-AOG-MAC01ibhedi esisigxina benzene Oxidation ukuya Maleic Anhydride catalyst
Ingcaciso yeMveliso:
I-AOG-MAC01Fixed-bed benzene Oxidation ukuya Maleic Anhydride catalyst ukuthatha
I-oxide exutyiweyo kwi-inert carrier, i-V2O5 kunye ne-MoO3 njengamacandelo asebenzayo, iyasetyenziswa
Kwibhedi esisigxina yebenzene oxidation kwi-maleic anhydride. I-catalyst ine-
Iimpawu zomsebenzi ophezulu, ukuqina okuphezulu, i-98% -99% izinga lokuguqulwa, kulungile
ukukhetha kunye ne-90% -95% isivuno. I-catalyst iphathwe ngokusebenza kwangaphambili
kunye nokusetyenzwa kobomi obude, ixesha lokuqala lokungeniswa liyancipha kakhulu,
Ubomi benkonzo yemveliso bufikelela kwiminyaka emibini okanye ngaphezulu.
Iimpawu zomzimba kunye neekhemikhali:izinto
isalathisi
Imbonakalo
Umbala omnyama-blue
Ukuxinana ngobuninzi,g/ml
0.75-0.81g/ml
Iinkcukacha zokwakheka, mm
Umngxunya oqhelekileyo 7 * 4 * 4
Indawo engaphezulu, ㎡/g
>0.1
Ukwakhiwa kweekhemikhali
V2O5, MoO3 kunye nezongezo
Amandla okutyumza
I-Axial10kg/inxalenye, i-radial5kg/inxalenye
Iimeko zokusebenza ezibhekiselele:
Ubushushu,℃
Inqanaba lokuqala 430-460 ℃, eqhelekileyo400-430 ℃
Isantya sesithuba, h -1
2000-2500
Ugxininiso lweBenzene
42g-48g /m³isiphumo esihle, 52g//m³ ingasetyenziswa
Inqanaba lomsebenzi
Izinga lokuguqulwa kweBenzene 98%-99%
1. Ukusebenzisa i-oyile-benzene yeyona nto ingcono kwi-catalyst, kuba i-thiophene kunye ne-sulphur iyonke kwi-benzene iya kunciphisa umsebenzi we-catalyst wokusebenza, emva kokuba isixhobo sisebenza ngokuqhelekileyo, i-coking ephezulu ye-benzene ingasetyenziswa.
2. Kwinkqubo, iqondo lokushisa kwindawo eshushu akufanele lidlule i-460 ℃.
3. Isantya sesithuba se-catalyst phakathi kwe-2000-2500 h -1 sinesiphumo esihle kakhulu. Kakade ke, ukuba isantya sendawo sikhulu kunolu, sikwasebenza kakuhle, kuba sisimsithezi esinesantya esiphezulu sendawo.
Ipakethe kunye nothutho:
Ngexesha lokugcinwa kunye nenkqubo yokuthutha, i-catalyst ibubungqina obupheleleyo bokufuma, ayinamanzi kwaye akufanele idlule kwiinyanga ezi-3 xa ibekwe emoyeni. Singakwazi ukupakisha ngokuguquguqukayo ngokweemfuno zabathengi. -
I-Gamma yasebenza i-alumina/i-Gamma Alumina Catalyst Abathwali/i-gamma alumina bead
Into
Iyunithi
Isiphumo
Isigaba seAlumina
Gamma Alumina
Ukuhanjiswa kobungakanani beNcam
D50
μm
88.71
<20μm
%
0.64
<40μm
%
9.14
>150μm
%
15.82
Ukuqulunqwa kwemichiza
Al2O3
%
99.0
SiO2
%
0.014
Na2O
%
0.007
Fe2O3
%
0.011
Ukusebenza koMzimba
BET
m²/g
196.04
Umthamo wePore
Ml/g
0.388
Ubungakanani bomndilili wePore
nm
7.92
Unizi lolwapho kuyiwa khona
g/ml
0.688
I-alumina ifunyaniswe ikhona ubuncinci iifom ezisi-8, ziyi-α- Al2O3, θ-Al2O3, γ- Al2O3, δ- Al2O3, η- Al2O3, χ- Al2O3, κ- Al2O3 kunye ne-ρ- Al2O3, iimpawu zabo zesakhiwo semacroscopic ngokwahlukeneyo. nazo zahlukile. I-alumina esebenzayo yeGamma yikhyubhiki evaliweyo epakishwe ngekristale, enganyibilikiyo emanzini, kodwa inyibilika kwiasidi kunye nealkali. I-alumina esebenzayo ye-gamma ibuthathaka kwinkxaso ye-asidi, inendawo ephezulu yokunyibilika eyi-2050 ℃, ijeli ye-alumina ekwimo ye-hydrate inokwenziwa kwi-oxide ene-porosity ephezulu kunye nomphezulu othile ophakamileyo, inezigaba zotshintsho kuluhlu olubanzi lobushushu. Kwiqondo lokushisa eliphezulu, ngenxa yokuphelelwa ngamanzi emzimbeni kunye ne-dehydroxylation, i-Al2O3surface ibonakala ilungelelanisa i-oksijini engaxutywanga (iziko le-alkali) kunye ne-aluminium (iziko le-asidi), kunye nomsebenzi we-catalytic. Ke ngoko, i-alumina ingasetyenziselwa njengomphathi, i-catalyst kunye ne-cocatalyst.I-alumina esebenzayo yeGamma inokuba ngumgubo, iigranules, imicu okanye ezinye. Singenza ngokwemfuno yakho.γ-Al2O3, yayibizwa ngokuba yi "alumina esebenzayo", luhlobo lwezixhobo eziqinileyo ezisasazekileyo, ngenxa yesakhiwo sayo sepore esihlengahlengiswayo, indawo enkulu yomphezulu othile, ukusebenza kakuhle kwe-adsorption, umphezulu kunye neenzuzo ze-asidi. kunye nokuzinza okuhle kwe-thermal, umphezulu we-microporous kunye neempawu ezifunekayo zesenzo se-catalytic, ngoko ke ibe yeyona nto isetyenziswa kakhulu, i-catalyst carrier kunye ne-chromatography carrier kumashishini ekhemikhali kunye ne-oyile, kwaye idlala indima ebalulekileyo kwi-oyile hydrocracking, ukulungiswa kwe-hydrogenation, ukuguqulwa kwe-hydrogenation, i-dehydrogenation reaction kunye nenkqubo yokucoca i-automobile exhaust.I-Gamma-Al2O3 isetyenziswa ngokubanzi njenge-catalyst carrier ngenxa yokulungelelaniswa kwesakhiwo sayo se-pore kunye ne-acidity yomhlaba. Xa i-γ- i-Al2O3 isetyenziswa njengomthwali, ngaphandle kwayo ingaba nemiphumo yokusabalalisa kunye nokuzinzisa amacandelo asebenzayo, inokubonelela ngeziko le-asidi yealkali esebenzayo, i-synergistic reaction kunye ne-catalytic active components. Ubume bepore kunye neepropathi zomphezulu we-catalyst zixhomekeke kwi-γ-Al2O3 carrier, ngoko ke umthwali wokusebenza okuphezulu unokufunyanwa kwimpendulo ethile ye-catalytic ngokulawula iipropathi ze-gamma alumina carrier.I-alumina esebenzayo ye-Gamma yenziwe ngokubanzi nge-precursor yayo ye-pseudo-boehmite nge-400 ~ 600℃ yokuphelelwa ngubushushu obuphezulu, ngoko ke iipropathi zomphezulu ze-physicochemical zimiselwa ikakhulu yi-precursor pseudo-boehmite, kodwa zininzi iindlela zokwenza i-pseudo-boehmite, kunye nemithombo eyahlukeneyo. ye-pseudo-boehmite ikhokelela ekuhlukeni kwe-gamma - i-Al2O3. Noko ke, kwezo catalysts kunye neemfuno ezikhethekileyo ukuba alumina carrier, bathembele kuphela kulawulo precursor pseudo-boehmite kunzima ukufikelela, kufuneka kuthatyathwe prophase ukulungiselela kunye post processing ukudibanisa iindlela ukulungisa iipropati alumina ukuhlangabezana neemfuno ezahlukeneyo. Xa iqondo lobushushu lingaphezulu kwe-1000 ℃ lisetyenziswayo, i-alumina yenzeka inguquko yesigaba esilandelayo: γ→δ→θ→α-Al2O3, phakathi kwabo γ, δ, θ zii-cubic ezisondeleleneyo zokupakisha, umahluko ulele kuphela kunikezelo lwe-ion aluminiyam kwi. i-tetrahedral kunye ne-octahedral, ngoko ke olu tshintsho lwesigaba alubangeli ukuhluka okukhulu kwezakhiwo. Ii-ion zeoksijini kwisigaba se-alpha zi-hexagonal ukupakisha ngokusondeleyo, amasuntswana e-aluminiyam oxide kukuhlangana kwakhona, indawo ethile yomphezulu inqabile kakhulu.
Ugcino:lKuphephe ukufuma, kunqande ukuskrola, ukujula kunye nokothuka okubukhali ngexesha lokuhamba, izibonelelo zemvula kufuneka zilungiswe.l Kufuneka igcinwe kwindawo eyomileyo nengena umoya ukunqanda ukosuleleka okanye ukufuma.Iphakheji:Uhlobo
Ibhegi yeplastikhi
Igubu
Igubu
Super isaka / Jumbo bag
Bead
25kg/55lb
25kg/55lb
150 kg/ 330 lb
750kg/1650lb
900kg/1980lb
1000kg/2200 lb
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Ijeli ye-alumina emile okwespherical/Ibhola ye-alumina esebenzayo/ibhola ye-alpha ye-alumina
Ijeli yeAlumina eMilo eSpherical esebenzayo
yokutofa kwi-Air dryerUbuninzi bobuninzi (g/1):690Ubungakanani beMesh: 98% 3-5mm (kubandakanya 3-4mm 64% kunye 4-5mm 34%)Ubushushu bokuhlaziya sicebisa ukuba buphakathi kwe-150 kunye ne-200℃Umthamo we-Euiqlibrium womphunga wamanzi yi-21%Umgangatho woVavanyo
HG/T3927-2007
Into yovavanyo
Umgangatho /SPEC
Iziphumo zovavanyo
Uhlobo
Amaso
Amaso
Al2O3(%)
≥92
92.1
LOI(%)
≤8.0
7.1
Unizi lolwapho kuyiwa khona(g/cm3)
≥0.68
0.69
BET(m2/g)
≥380
410
Umthamo wePore(cm3/g)
≥0.40
0.41
Amandla Okutyumza(N/G)
≥130
136
Amanzi adsorption(%)
≥50
53.0
Ilahleko kwi-Atrition(%)
≤0.5
0.1
Ubungakanani obufanelekileyo(%)
≥90
95.0
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Inkxaso ye-alpha alumina catalyst
I-α-Al2O3 yimpahla ene-porous, ehlala isetyenziselwa ukuxhasa i-catalysts, i-adsorbents, izinto zokuhlukana kwesigaba segesi, njl. njl . Ubungakanani bepore ye-α-Al2O3 ye-catalyst carrier inkulu kakhulu kunendlela ye-molecular free, kwaye ukuhanjiswa kufana, ngoko ke ingxaki yangaphakathi yokusabalalisa okubangelwa ubungakanani obuncinci be-pore kwi-catalytic reaction system inokupheliswa ngcono, kunye ne-oxidation enzulu. iimpendulo zecala zinokuncitshiswa kwinkqubo ngenjongo ye-oxidation ekhethiweyo. Ngokomzekelo, i-catalyst yesilivere esetyenziselwa i-ethylene oxidation kwi-ethylene oxide isebenzisa i-α-Al2O3 njengomthwali. Ihlala isetyenziswa kwi-catalytic reactions kunye nobushushu obuphezulu kunye nolawulo lokusasazwa kwangaphandle.
Idatha yeMveliso
Indawo ethile 4-10 m²/g Umthamo wePore 0.02-0.05 g/cm³ Ubume I-Spherical, cylindrical, i-rascated ring, njl UAlfa hlambulula ≥99% Na2O3 ≤0.05% SiO2 ≤0.01% Fe2O3 ≤0.01% Imveliso ingenziwa ngokwezifiso ngokweemfuno zesalathisi